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Principles of Iodometric Titration
Iodometric titration is a type of redox titration where iodine serves as an oxidizing agent. It is commonly used in analytical chemistry to determine the concentration of reducing agents like Vitamin C (ascorbic acid).
The titration proceeds as follows:
- Iodine solution is gradually added to a sample containing Vitamin C.
- Vitamin C reacts with iodine, causing the iodine to be reduced to iodide ions.
- When all Vitamin C has been oxidized, additional iodine will remain in solution.
- The starch indicator, which does not react with Vitamin C, forms a blue complex with excess iodine.
- The appearance of the blue color marks the endpoint of the titration.
Chemical reaction between iodine and Vitamin C:
I2 + C6H8O6 → 2I- + C6H6O6 + 2H+
This titration method is valuable for determining Vitamin C content in foods, beverages, and pharmaceutical products.